Archive for February 6th, 2012

An exothermic E2 elimination: an unusual intrinsic reaction coordinate.

Monday, February 6th, 2012

The previous post explored why E2 elimination reactions occur with an antiperiplanar geometry for the transition state. Here I have tweaked the initial reactant to make the overall reaction exothermic rather than endothermic as it was before. The change is startling.

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