Climbers scale Mt. Everest, because its there, and chemists have their own version of this. Ever since G. N. Lewis introduced the concept of the electron-pair bond in 1916, the idea of a bond as having a formal bond-order has been seen as a useful way of thinking about molecules. The initial menagerie of single, double and triple formal bond orders (with a few half sizes) was extended in the 1960s to four, and in 2005 to five. Since then, something of a race has developed to produce the compound with the shortest quintuple bond. One of the candidates for this honour is shown below (2008, DOI: 10.1002/anie.200803859) which is a crystalline species (a few diatomics which exist in the gas phase are also candidates; for other reviews of the topic seeĀ 10.1038/nchem.359, 10.1021/ja905035f and 10.1246/cl.2009.1122).