Did the authors try resolving the delta G
values into H and S for any example, using
variable temperature analysis of a system
(we find the program gNMR excellent for this
Although this normally leads to the same G
values, such a deconvolution often throws
up quite interesting deltaS values (assuming
that the value can be trusted, it is notoriously
error prone), and can often pick up steric
or stereoelectronic effects in such systems.
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