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Web-enhanced Table 2.a Polymerisation sequence growing a single chain or two chains.
Systemb ΔG†298, kcal mol-1 Digital Repositoryc Load 1 Load 1_chair +2CO2+2CHO 0.0 -0.6 to-8497 to-9150 Load 2 Load 2_chair +2CO2+2CHO -5.9 -6.1 to-8565 to-9152 Load 21 Load 23 (boat) Load 23 (chair) -24.9 (-15.7)d -21.8(-12.5)d -21.8(-12.5)d to-9322 to-9340 to-9266
aIf a Java-enabled Web browser is used, 3D models will be generated using Jmol, and are invoked by clicking on any of the labelled links. The resulting display can also be controlled by a pull down menu produced by a right-mouse click in the right hand viewing window, from which individual coordinate files can also be acquired. If your device is not Java-enabled, the diagrams will be generated using ChemDoodle Web components making use of WebGL (white background) or no use (black background). cOAI-PMH compliant Digital repository identifier, resolved as e.g. http://dx.doi.org/10042/to-5700