{"id":936,"date":"2009-10-02T23:03:23","date_gmt":"2009-10-02T22:03:23","guid":{"rendered":"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936"},"modified":"2009-10-06T09:13:40","modified_gmt":"2009-10-06T08:13:40","slug":"full-circle-with-carbon-valencies","status":"publish","type":"post","link":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936","title":{"rendered":"Full circle with carbon hypervalencies"},"content":{"rendered":"<div class=\"kcite-section\" kcite-section-id=\"936\">\n<p>The previous post talked about making links or connections. And part of the purpose for presenting this chemistry as a blog is to expose how these connections are made, or or less as it happens in real time (and\u00a0not the chronologically sanitized version of discovery that most research papers are).\u00a0So each post represents an evolution or mutation from the previous one. To recapitulate, we have seen how the idea of  cyclopentadienyl anion as a ligand for a dipositive carbon atom has evolved. Let us move in yet another direction; the cyclobutadienyl dianion.\u00a0\u00a0This ligand has recently been shown to bind Mg<sup>2+<\/sup> (DOI: <a href=\"http:\/\/dx.doi.org\/10.1002\/ejic.200800066\" target=\"_blank\">10.1002\/ejic.200800066<\/a>), so why not He<sup>2+<\/sup>?\u00a0And picking up again the previous theme,  we will then protonate the bound complex. The result now is a monocation, and it has the C<sub>4v<\/sub>-symmetric structure shown below (DOI: <a href=\"http:\/\/hdl.handle.net\/10042\/to-2438\" target=\"references\">10042\/to-2438<\/a>). This bears some resemblance to pyramidane, a neutral \u00a0C<sub>5<\/sub>H<sub>4<\/sub> compound with hemispherical carbon reported in 2001 (DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/jp011642r\" target=\"references\">10.1021\/jp011642r<\/a>) which is also a stable minimum in the potential energy surface.<\/p>\n<div id=\"attachment_939\" style=\"width: 255px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-939\" class=\"size-full wp-image-939\" title=\"c4\" src=\"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2009\/10\/c4.jpg\" alt=\"C4-symmetric pentavalent carbon\" width=\"245\" height=\"231\" \/><p id=\"caption-attachment-939\" class=\"wp-caption-text\">C4-symmetric pentavalent carbon<\/p><\/div>\n<p>Now, the apical C-C bonds have shrunk to 1.58\u00c5, the trampoline mode is increased to 970 cm<sup>-1<\/sup> and the apical C-H frequency to 3291 cm<sup>-1<\/sup>. The apical C-C value for the AIM bond critical point \u03c1(r) is up 0.195 au and the disynaptic basin integration in that region is now 1.1 electrons. Replacing the apical C-H by C-F further strengthens the system (DOI: <a href=\"http:\/\/hdl.handle.net\/10042\/to-2447\" target=\"references\">10042\/to-2447<\/a>); the apical C-C bonds contract slightly to 1.57\u00c5, the bouncing castle\/trampoline mode shoots up to \u03bd 1595 cm<sup>-1 <\/sup>, \u03c1(r) reaches 0.201 au and the disynaptic basins 1.25 electrons. With this latter system, the  C-F disynaptic basin contains only 1.08 electrons, suggesting it is similar in nature to the other four bonds surrounding the apical carbon, i.e. this carbon is surrounded by five more or less equivalent bonds. The <em>pseudo-halogen<\/em> CN can also replace the\u00a0F (DOI: <a href=\"http:\/\/hdl.handle.net\/10042\/to-2449\" target=\"references\">10042\/to-2449<\/a>)\u00a0to similar effect (\u03c1(r)<sub>C-C<\/sub> 0.190, \u03c1(r)<sub>C-CN<\/sub> 0.290).<\/p>\n<table border=\"0\">\n<tbody>\n<tr>\n<td>\n<p><div id=\"attachment_946\" style=\"width: 215px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-946\" class=\"size-full wp-image-946\" title=\"c4-aim\" src=\"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2009\/10\/c4-aim.jpg\" alt=\"AIM Analysis\" width=\"205\" height=\"200\" \/><p id=\"caption-attachment-946\" class=\"wp-caption-text\">AIM Analysis<\/p><\/div><\/td>\n<td><div id=\"attachment_954\" style=\"width: 272px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-954\" class=\"size-full wp-image-954\" title=\"c4-elf\" onclick=\"jmolInitialize('..\/Jmol\/');jmolSetAppletColor('white');jmolApplet([450,450],'load wp-content\/uploads\/2009\/10\/C4-CH-elf.mol; frame 1; zoom 100;spin 3;');\" src=\"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2009\/10\/c4-elf.jpg\" alt=\"ELF Basin centroids\" width=\"262\" height=\"231\" \/><p id=\"caption-attachment-954\" class=\"wp-caption-text\">ELF Basin centroids. Click for 3D<\/p><\/div><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>We are back to pentavalent, pentacoordinate carbon again,  but we have gradually optimized the properties of the system for five short C-C bonds surrounding one carbon atom, and the largest electron density and disynaptic basin integration. Whilst the sentiments expressed by Hoffmann, Schleyer and Schaefer (DOI: <a href=\"http:\/\/dx.doi.org\/10.1002\/anie.200801206\" target=\"references\">10.1002\/anie.200801206<\/a>) for more realism in predicting molecules must not be ignored, it is to be hoped that the original suggestions made here will lead to the discovery of realistic and makeable molecules exhibiting true C-C hypervalency.<\/p>\n<!-- kcite active, but no citations found -->\n<\/div> <!-- kcite-section 936 -->","protected":false},"excerpt":{"rendered":"<p>The previous post talked about making links or connections. And part of the purpose for presenting this chemistry as a blog is to expose how these connections are made, or or less as it happens in real time (and\u00a0not the chronologically sanitized version of discovery that most research papers are).\u00a0So each post represents an evolution [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"activitypub_content_warning":"","activitypub_content_visibility":"","activitypub_max_image_attachments":5,"activitypub_interaction_policy_quote":"anyone","activitypub_status":"","footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":false,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[7,4],"tags":[2649,2648,142,427],"ppma_author":[2661],"class_list":["post-936","post","type-post","status-publish","format-standard","hentry","category-hypervalency","category-interesting-chemistry","tag-hypervalency","tag-interesting-chemistry","tag-potential-energy-surface","tag-pseudo"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.3 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Full circle with carbon hypervalencies - Henry Rzepa&#039;s Blog<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936\" \/>\n<meta property=\"og:locale\" content=\"en_GB\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Full circle with carbon hypervalencies - Henry Rzepa&#039;s Blog\" \/>\n<meta property=\"og:description\" content=\"The previous post talked about making links or connections. And part of the purpose for presenting this chemistry as a blog is to expose how these connections are made, or or less as it happens in real time (and\u00a0not the chronologically sanitized version of discovery that most research papers are).\u00a0So each post represents an evolution [&hellip;]\" \/>\n<meta property=\"og:url\" content=\"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936\" \/>\n<meta property=\"og:site_name\" content=\"Henry Rzepa&#039;s Blog\" \/>\n<meta property=\"article:published_time\" content=\"2009-10-02T22:03:23+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2009-10-06T08:13:40+00:00\" \/>\n<meta property=\"og:image\" content=\"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2009\/10\/c4.jpg\" \/>\n<meta name=\"author\" content=\"Henry Rzepa\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Henry Rzepa\" \/>\n\t<meta name=\"twitter:label2\" content=\"Estimated reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"2 minutes\" \/>\n<!-- \/ Yoast SEO plugin. -->","yoast_head_json":{"title":"Full circle with carbon hypervalencies - Henry Rzepa&#039;s Blog","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936","og_locale":"en_GB","og_type":"article","og_title":"Full circle with carbon hypervalencies - Henry Rzepa&#039;s Blog","og_description":"The previous post talked about making links or connections. And part of the purpose for presenting this chemistry as a blog is to expose how these connections are made, or or less as it happens in real time (and\u00a0not the chronologically sanitized version of discovery that most research papers are).\u00a0So each post represents an evolution [&hellip;]","og_url":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936","og_site_name":"Henry Rzepa&#039;s Blog","article_published_time":"2009-10-02T22:03:23+00:00","article_modified_time":"2009-10-06T08:13:40+00:00","og_image":[{"url":"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2009\/10\/c4.jpg","type":"","width":"","height":""}],"author":"Henry Rzepa","twitter_card":"summary_large_image","twitter_misc":{"Written by":"Henry Rzepa","Estimated reading time":"2 minutes"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"Article","@id":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936#article","isPartOf":{"@id":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936"},"author":{"name":"Henry Rzepa","@id":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/#\/schema\/person\/2b40f7b9c872a4dc1547e040a11b6281"},"headline":"Full circle with carbon hypervalencies","datePublished":"2009-10-02T22:03:23+00:00","dateModified":"2009-10-06T08:13:40+00:00","mainEntityOfPage":{"@id":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936"},"wordCount":432,"commentCount":0,"image":{"@id":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936#primaryimage"},"thumbnailUrl":"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2009\/10\/c4.jpg","keywords":["Hypervalency","Interesting chemistry","potential energy surface","pseudo"],"articleSection":["Hypervalency","Interesting chemistry"],"inLanguage":"en-GB","potentialAction":[{"@type":"CommentAction","name":"Comment","target":["https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936#respond"]}]},{"@type":"WebPage","@id":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936","url":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=936","name":"Full circle with carbon hypervalencies - 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