{"id":14692,"date":"2015-10-14T14:29:55","date_gmt":"2015-10-14T13:29:55","guid":{"rendered":"http:\/\/www.ch.imperial.ac.uk\/rzepa\/blog\/?p=14692"},"modified":"2015-10-16T10:14:31","modified_gmt":"2015-10-16T09:14:31","slug":"impressions-of-china-2-the-colour-of-porcelain","status":"publish","type":"post","link":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=14692","title":{"rendered":"Impressions of China 2: The colour of porcelain."},"content":{"rendered":"<div class=\"kcite-section\" kcite-section-id=\"14692\">\n<p>In Jingdezhen an Imperial Kiln was built in 1369 to produce porcelain that was &#8220;white as jade, thin as paper, bright as a mirror and tuneful as a bell&#8221;. It&#8217;s the colours of the glazes that caught my eye, achieved by a combination of oxidative and reductive firing in the kiln, coupled with exquisite control of the temperature.<\/p>\n<p>The photo below represents the glaze master weighing out the transition metal salts required to produce the colours, with abacus to hand! The labels on the bottles are not translated (I forgot to load up the camera-based translator onto my\u00a0iPad, which I am using to write this post). Question: what colours does oxidative or reductive firing with vanadium salts produce?<\/p>\n<p><a href=\"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image6.jpeg\"><img decoding=\"async\" class=\"aligncenter size-full wp-image-14699\" src=\"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image6.jpeg\" alt=\"image\" width=\"440\" srcset=\"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image6.jpeg 2096w, https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image6-300x224.jpeg 300w, https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image6-1024x764.jpeg 1024w, https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image6-900x671.jpeg 900w\" sizes=\"(max-width: 2096px) 100vw, 2096px\" \/><\/a><\/p>\n<p><a href=\"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image5.jpeg\"><img decoding=\"async\" class=\"aligncenter size-full wp-image-14697\" src=\"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image5.jpeg\" alt=\"image\" width=\"440\" srcset=\"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image5.jpeg 1681w, https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image5-300x84.jpeg 300w, https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image5-1024x287.jpeg 1024w, https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image5-900x252.jpeg 900w\" sizes=\"(max-width: 1681px) 100vw, 1681px\" \/><\/a><\/p>\n<p>And in Tunxi in the old village of Xidi the bridge made famous by the film <em>Crouching Tiger, Hidden Dragon<\/em>. <a href=\"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image7.jpeg\"><img decoding=\"async\" class=\"aligncenter size-full wp-image-14701\" src=\"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image7.jpeg\" alt=\"image\" width=\"440\" srcset=\"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image7.jpeg 1630w, https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image7-300x246.jpeg 300w, https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image7-1024x839.jpeg 1024w, https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image7-900x737.jpeg 900w\" sizes=\"(max-width: 1630px) 100vw, 1630px\" \/><\/a><\/p>\n<!-- kcite active, but no citations found -->\n<\/div> <!-- kcite-section 14692 -->","protected":false},"excerpt":{"rendered":"<p>In Jingdezhen an Imperial Kiln was built in 1369 to produce porcelain that was &#8220;white as jade, thin as paper, bright as a mirror and tuneful as a bell&#8221;. It&#8217;s the colours of the glazes that caught my eye, achieved by a combination of oxidative and reductive firing in the kiln, coupled with exquisite control [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"activitypub_content_warning":"","activitypub_content_visibility":"","activitypub_max_image_attachments":5,"activitypub_interaction_policy_quote":"anyone","activitypub_status":"","footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[565,4],"tags":[],"ppma_author":[2661],"class_list":["post-14692","post","type-post","status-publish","format-standard","hentry","category-historical","category-interesting-chemistry"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.5 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Impressions of China 2: The colour of porcelain. - Henry Rzepa&#039;s Blog<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=14692\" \/>\n<meta property=\"og:locale\" content=\"en_GB\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Impressions of China 2: The colour of porcelain. - Henry Rzepa&#039;s Blog\" \/>\n<meta property=\"og:description\" content=\"In Jingdezhen an Imperial Kiln was built in 1369 to produce porcelain that was &#8220;white as jade, thin as paper, bright as a mirror and tuneful as a bell&#8221;. It&#8217;s the colours of the glazes that caught my eye, achieved by a combination of oxidative and reductive firing in the kiln, coupled with exquisite control [&hellip;]\" \/>\n<meta property=\"og:url\" content=\"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=14692\" \/>\n<meta property=\"og:site_name\" content=\"Henry Rzepa&#039;s Blog\" \/>\n<meta property=\"article:published_time\" content=\"2015-10-14T13:29:55+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2015-10-16T09:14:31+00:00\" \/>\n<meta property=\"og:image\" content=\"http:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2015\/10\/image6.jpeg\" \/>\n<meta name=\"author\" content=\"Henry Rzepa\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Henry Rzepa\" \/>\n\t<meta name=\"twitter:label2\" content=\"Estimated reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"1 minute\" \/>\n<!-- \/ Yoast SEO plugin. -->","yoast_head_json":{"title":"Impressions of China 2: The colour of porcelain. - Henry Rzepa&#039;s Blog","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=14692","og_locale":"en_GB","og_type":"article","og_title":"Impressions of China 2: The colour of porcelain. - Henry Rzepa&#039;s Blog","og_description":"In Jingdezhen an Imperial Kiln was built in 1369 to produce porcelain that was &#8220;white as jade, thin as paper, bright as a mirror and tuneful as a bell&#8221;. 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&#8220;enables a non-enzymatic Krebs cycle precursor&#8221;","author":"Henry Rzepa","date":"March 19, 2017","format":false,"excerpt":"The Wikipedia entry on peroxydisulfate is quite short (as of today). 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The article reports that \"in the presence of\u2026","rel":"","context":"In &quot;crystal_structure_mining&quot;","block_context":{"text":"crystal_structure_mining","link":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?cat=1745"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2017\/03\/157-1024x364.jpg?resize=350%2C200","width":350,"height":200},"classes":[]},{"id":11246,"url":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=11246","url_meta":{"origin":14692,"position":1},"title":"Patterns of behaviour: serendipity in action for enantiomerisation of F-S-S-Cl","author":"Henry Rzepa","date":"September 19, 2013","format":false,"excerpt":"Paul Schleyer sent me an email about a pattern he had spotted, between my post on F3SSF and some work he and\u00a0Michael Mauksch had done 13 years ago with the intriguing title \"Demonstration of Chiral Enantiomerization in a Four-Atom Molecule\". Let me explain the connection, but also to follow-up further\u2026","rel":"","context":"In &quot;Interesting chemistry&quot;","block_context":{"text":"Interesting chemistry","link":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?cat=4"},"img":{"alt_text":"FSSCl","src":"https:\/\/i0.wp.com\/www.ch.imperial.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2013\/09\/FSSCl.gif?resize=350%2C200","width":350,"height":200},"classes":[]},{"id":6708,"url":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=6708","url_meta":{"origin":14692,"position":2},"title":"Reductive ozonolysis: the interesting step.","author":"Henry Rzepa","date":"May 7, 2012","format":false,"excerpt":"The mechanism of the reaction of alkenes known as ozonolysis was first set out in its modern form by Criegee. The crucial steps, (a), (b) and (d), are all pericyclic cycloaddition\/eliminations. The last step (e) is known as reductive ozonolysis, and this step is often treated as an afterthought, part\u2026","rel":"","context":"In &quot;Interesting chemistry&quot;","block_context":{"text":"Interesting chemistry","link":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?cat=4"},"img":{"alt_text":"","src":"http:\/\/www.ch.imperial.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2012\/05\/ozonolysis.svg","width":350,"height":200},"classes":[]},{"id":2687,"url":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=2687","url_meta":{"origin":14692,"position":3},"title":"Hypervalency:  Third time lucky?","author":"Henry Rzepa","date":"October 23, 2010","format":false,"excerpt":"One approach to reporting science which is perhaps better suited to the medium of a blog than a conventional journal article is the opportunity to follow ideas in unexpected, even unconventional directions. Thus my third attempt, like a dog worrying a bone, to explore hypervalency. I have, somewhat to my\u2026","rel":"","context":"In &quot;Hypervalency&quot;","block_context":{"text":"Hypervalency","link":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?cat=7"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2010\/10\/I8.jpg?resize=350%2C200","width":350,"height":200},"classes":[]},{"id":12539,"url":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=12539","url_meta":{"origin":14692,"position":4},"title":"An original chemistry lab from the early 19th century.","author":"Henry Rzepa","date":"May 18, 2014","format":false,"excerpt":"Not a computer in sight! I refer to a chemistry lab from the 1800s I was recently taken to, where famous french chemists such as Joseph Gay-Lussac, Michel Chevreul and Edmond Fremy were professors. Although not used for chemistry any more, it is an incredible treasure trove of objects. Here\u2026","rel":"","context":"In &quot;Historical&quot;","block_context":{"text":"Historical","link":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?cat=565"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":19723,"url":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?p=19723","url_meta":{"origin":14692,"position":5},"title":"Why do flowers such as roses, peonies, dahlias, delphiniums (etc), exhibit so many shades of colours?","author":"Henry Rzepa","date":"June 18, 2018","format":false,"excerpt":"It was about a year ago that I came across a profusion of colour in my local Park. Although colour in fact was the topic that sparked my interest in chemistry many years ago (the fantastic reds produced by diazocoupling reactions), I had never really tracked down the origin of\u2026","rel":"","context":"In &quot;Interesting chemistry&quot;","block_context":{"text":"Interesting chemistry","link":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/?cat=4"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/www.ch.ic.ac.uk\/rzepa\/blog\/wp-content\/uploads\/2018\/06\/delphindin-1024x856.jpg?resize=350%2C200&ssl=1","width":350,"height":200},"classes":[]}],"jetpack_likes_enabled":false,"authors":[{"term_id":2661,"user_id":1,"is_guest":0,"slug":"admin","display_name":"Henry Rzepa","avatar_url":"https:\/\/secure.gravatar.com\/avatar\/897b6740f7f599bca7942cdf7d7914af5988937ae0e3869ab09aebb87f26a731?s=96&d=blank&r=g","0":null,"1":"","2":"","3":"","4":"","5":"","6":"","7":"","8":""}],"_links":{"self":[{"href":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/index.php?rest_route=\/wp\/v2\/posts\/14692","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=14692"}],"version-history":[{"count":10,"href":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/index.php?rest_route=\/wp\/v2\/posts\/14692\/revisions"}],"predecessor-version":[{"id":14706,"href":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/index.php?rest_route=\/wp\/v2\/posts\/14692\/revisions\/14706"}],"wp:attachment":[{"href":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=14692"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=14692"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=14692"},{"taxonomy":"author","embeddable":true,"href":"https:\/\/www.ch.ic.ac.uk\/rzepa\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fppma_author&post=14692"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}