References

 

1) Beilstein Commander

Nuclear Magnetic Resonance: Journal; Goto et al.; TETAB; Tetrahedron; 21; 1965; 2059; 2072

Infrared Spectra: Journal; Goto et al.; TETRAB; Tetrahedron; 21; 1965; 2059; 2081

Related Structure: Journal; Kishi et al.; JACSAT; J. Amer. Chem. Soc.; 94; 1972; 9219

Journal; Goto et al.; TELEAY; Tetrahedron Lett.; 1964; 779; TETRAB; Tetrahedron; 21; 1965; 2059.

Journal; Woodward; PACHAS; Pure Appl. Chem.; 9; 1964; 49.

Journal; Tsuda et al.; CPBTAL; Chem. Pharm. Bull.; 12; 1964;1357.

Journal; Furusaki et al.; BCSJA8; Bull. Chem. Soc. Jpn.; 43; 1970; 3332.

 

Melting Point: Journal; Goto et al.; TeTRAB; Tetrahedron; 21; 1965; 2059, 2071, 2081

 

2) Google

Bio Synthesis:

Kotaki and Shimizu, Journal of the American Chemical Society 115:3,829

Organic Synthesis:

www.chm.bris.ac.uk/motm/ttx/ttx.htm

Treatment:

www.emedicine.com/emerg/topic576.htm

 

4) Chemfinder database

Woodward, R. B., Pure Appl. Chem. 1964, 9,49-74

GotoT, Kishi Y et al. Tetrahedron 1965, 21,2059-2088

Tsuda, K., Ikuma, S. et al. Chem. Pharm. Bull 1964, 12, 1357-1374

Kishi, Y. et al. J. Am. Chem. Soc. 1972

 

6) Cambridge Crystal Structure Database

 

7) Corina service

3D molecular coordinates of TTX is converted from a 1D smile string (Chemdraw)

 

8) gNMR

 

9) M.J. Caterina et al.
"The capsaicin receptor: a heat-activated ion channel in the pain pathway," Nature, 389:816-24, 1997.

 

10) A.N. Akopian et al.
"A tetrodotoxin-resistant voltage-gated sodium channel expressed by sensory neurons," Nature,379:257-62, 1996.

 

11) L. Sangameswaran et al.
"Structure and function of a novel voltage-gated, tetrodotoxin-resistant sodium channel specific to sensory neurons," Journal of Biological Chemistry, 271:953-6, 1996.

 

12) S. Tate et al.
"Two sodium channels contribute to the TTX-R sodium current in primary sensory neurons,"Nature Neuroscience, 1:653-5, December 1998.