$Version: 4 $Totobjs: 22 $Pen_RGB2Color: 0 0 0 $Fill_RGB2Color: 0 0 0 $Font: "Times New Roman" 120 0 $Obj: text $Transparent: $RxnAtch: -1 -1 $Obj_coords: 1586 459 1698 601 $MDLEdittext: 1 000b {\rtf1\defformat\pc {\fonttbl {\f3692\nil Times New Roman;} } \plain \f3692\fs24 (i) } $Obj: text $Transparent: $RxnAtch: -1 -1 $Obj_coords: 1744 1297 2897 1462 $MDLEdittext: 1 000b {\rtf1\defformat\pc {\fonttbl {\f3692\nil Times New Roman;} {\f2604\nil Times New Roman;} } \plain \f3692\fs24 (i) 2 SiR \plain \f2604\fs24\dn6 3 \plain \f3692\fs24 Cl, thf or Et \plain \f2604\fs24\dn6 2 \plain \f3692\fs24 O } $Obj: text $Transparent: $RxnAtch: -1 -1 $Obj_coords: 1738 1096 2906 1238 $MDLEdittext: 1 000b {\rtf1\defformat\pc {\fonttbl {\f3692\nil Times New Roman;} } \plain \f3692\fs24 Reagents and conditions } $Obj: text $Transparent: $RxnAtch: -1 -1 $Obj_coords: 1805 563 2831 735 $MDLEdittext: 1 000b {\rtf1\defformat\pc {\fonttbl {\f3692\nil Times New Roman;} {\f2608\nil Symbol;} {\f484\nil Times New Roman;} } \plain \f3692\fs24 Fe( \plain \f2608\fs24 h \plain \f3692\fs24 -C \plain \f484\fs24\dn6 5 \plain \f3692\fs24 H \plain \f484\fs24\dn6 4 \plain \f3692\fs24 Li.tmeda) \plain \f484\fs24\dn6 2 } $Obj: line $ArrowDir: 1 $ArrowStyle: 1 $ArrowSize: 57 64 cm cm $RxnAtch: -1 -1 $Obj_coords: 2856 655 3254 655 $Obj: text $Transparent: $RxnAtch: -1 -1 $Obj_coords: 2951 467 3093 609 $MDLEdittext: 1 000b {\rtf1\defformat\pc {\fonttbl {\f1576\nil Times New Roman;} {\f3692\nil Times New Roman;} } \plain \f3692\fs24 (ii) } $Obj: text $Transparent: $RxnAtch: -1 -1 $Obj_coords: 1736 1499 2927 1664 $MDLEdittext: 1 000b {\rtf1\defformat\pc {\fonttbl {\f3692\nil Times New Roman;} {\f1572\nil Times New Roman;} {\f1400\nil Times New Roman;} } \plain \f3692\fs24 (ii) 2 SiR \plain \f1572\fs24\dn6 2 \plain \f3692\fs24 Cl \plain \f1572\fs24\dn6 2 \plain \f3692\fs24 , thf, -78 \plain \f1400\fs24\up6 o \plain \f3692\fs24 C } $Obj: mol $RxnAtch: -1 -1 $Begsketch: $Totobjs: 23 $Obj: atom $Atom_coords: 3331.50902 321.43262 $Atom_zcoord: -130.21019 $Atom_symbol: "C" $Atom_number: 6 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 3330.68895 431.77271 $Atom_zcoord: 128.89313 $Atom_symbol: "C" $Atom_number: 7 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 3598.29027 466.37085 $Atom_zcoord: 209.59862 $Atom_symbol: "C" $Atom_number: 8 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 3764.44188 377.40709 $Atom_zcoord: 0.35602 $Atom_symbol: "C" $Atom_number: 9 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 3599.58861 287.83214 $Atom_zcoord: -209.65250 $Atom_symbol: "C" $Atom_number: 10 $Atom_marginwidth: 30 $Obj: bond $Bond_atoms: 0 1 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 1 2 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 2 3 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 3 4 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 4 0 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: atom $Atom_coords: 3354.50902 839.43262 $Atom_zcoord: -130.21019 $Atom_symbol: "C" $Atom_number: 11 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 3353.68895 949.77271 $Atom_zcoord: 128.89313 $Atom_symbol: "C" $Atom_number: 12 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 3621.29027 984.37085 $Atom_zcoord: 209.59862 $Atom_symbol: "C" $Atom_number: 13 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 3787.44188 895.40709 $Atom_zcoord: 0.35602 $Atom_symbol: "C" $Atom_number: 14 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 3622.58861 805.83214 $Atom_zcoord: -209.65250 $Atom_symbol: "C" $Atom_number: 15 $Atom_marginwidth: 30 $Obj: bond $Bond_atoms: 10 11 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 11 12 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 12 13 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 13 14 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 14 10 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: atom $Atom_coords: 4037.00000 647.00000 $Atom_alias: "SiR2" $Atom_number: 16 $Atom_marginwidth: 30 $Obj: bond $Bond_atoms: 3 20 $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 20 13 $Bond_hash_spacing: 20 $Endsketch: $Obj: ellipse $Transparent: $Fill_style: 0 $Obj_coords: 3400 340 3662 415 $Obj: ellipse $Transparent: $Fill_style: 0 $Obj_coords: 3415 857 3677 932 $Obj: line $ArrowStyle: 1 $ArrowSize: 57 64 cm cm $RxnAtch: -1 -1 $Obj_coords: 3549 744 3549 909 $Obj: line $ArrowStyle: 1 $ArrowSize: 57 64 cm cm $RxnAtch: -1 -1 $Obj_coords: 3542 392 3542 557 $Obj: text $Transparent: $RxnAtch: -1 -1 $Obj_coords: 3498 572 3618 714 $MDLEdittext: 1 000b {\rtf1\defformat\pc {\fonttbl {\f3692\nil Times New Roman;} } \plain \f3692\fs24 Fe } $Obj: mol $RxnAtch: -1 -1 $Begsketch: $Totobjs: 12 $Obj: atom $Atom_coords: 571.50902 846.43262 $Atom_zcoord: -130.21019 $Atom_symbol: "C" $Atom_number: 11 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 570.68895 956.77271 $Atom_zcoord: 128.89313 $Atom_symbol: "C" $Atom_number: 12 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 838.29027 991.37085 $Atom_zcoord: 209.59862 $Atom_symbol: "C" $Atom_number: 13 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 1004.44188 902.40709 $Atom_zcoord: 0.35602 $Atom_symbol: "C" $Atom_number: 14 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 839.58861 812.83202 $Atom_zcoord: -209.65250 $Atom_symbol: "C" $Atom_number: 15 $Atom_marginwidth: 30 $Obj: bond $Bond_atoms: 0 1 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 1 2 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 2 3 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 3 4 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 4 0 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: atom $Atom_coords: 1287.00000 902.00000 $Atom_alias: "SiR3" $Atom_number: 22 $Atom_marginwidth: 30 $Obj: bond $Bond_atoms: 3 10 $Bond_hash_spacing: 20 $Endsketch: $Obj: polygon $Transparent: $Fill_style: 0 $Poly_points: 4 754 364 885 402 754 439 623 402 $Poly_smoothed: $Obj: ellipse $Transparent: $Fill_style: 0 $Obj_coords: 632 864 894 939 $Obj: line $ArrowStyle: 1 $ArrowSize: 57 64 cm cm $RxnAtch: -1 -1 $Obj_coords: 766 751 766 916 $Obj: line $ArrowStyle: 1 $ArrowSize: 57 64 cm cm $RxnAtch: -1 -1 $Obj_coords: 759 399 759 564 $Obj: text $Transparent: $RxnAtch: -1 -1 $Obj_coords: 715 579 835 721 $MDLEdittext: 1 000b {\rtf1\defformat\pc {\fonttbl {\f3692\nil Times New Roman;} } \plain \f3692\fs24 Fe } $Obj: mol $RxnAtch: -1 -1 $Begsketch: $Totobjs: 12 $Obj: atom $Atom_coords: 954.47803 457.40410 $Atom_zcoord: 128.60406 $Atom_symbol: "C" $Atom_number: 17 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 953.32689 347.36565 $Atom_zcoord: -130.62630 $Atom_symbol: "C" $Atom_number: 18 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 685.11768 313.78870 $Atom_zcoord: -209.72861 $Atom_symbol: "C" $Atom_number: 19 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 520.56128 403.08240 $Atom_zcoord: 0.63036 $Atom_symbol: "C" $Atom_number: 20 $Atom_marginwidth: 30 $Obj: atom $Atom_coords: 687.00853 491.83899 $Atom_zcoord: 209.72787 $Atom_symbol: "C" $Atom_number: 21 $Atom_marginwidth: 30 $Obj: bond $Bond_atoms: 0 1 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 1 2 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 2 3 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 3 4 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: bond $Bond_atoms: 4 0 $Bond_topo: ring $Bond_hash_spacing: 20 $Obj: atom $Atom_coords: 237.00000 403.00000 $Atom_alias: "R3Si" $Atom_number: 23 $Atom_marginwidth: 30 $Obj: bond $Bond_atoms: 3 10 $Bond_hash_spacing: 20 $Endsketch: $Obj: line $ArrowDir: 2 $ArrowStyle: 1 $ArrowSize: 57 64 cm cm $RxnAtch: -1 -1 $Obj_coords: 1388 656 1786 656 $Obj: text $Transparent: $RxnAtch: -1 -1 $Obj_coords: 3323 1072 3787 1237 $MDLEdittext: 1 000b {\rtf1\defformat\pc {\fonttbl {\f3692\nil Times New Roman;} {\f1436\nil Times New Roman;} } \plain \f3692\fs24 + SiR \plain \f1436\fs24\dn6 2 \plain \f3692\fs24 Cl \plain \f1436\fs24\dn6 2 } $Endsketch: